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Peptide Modifications intermediate

Disulfide Bonds in Peptides

Overview of disulfide bond formation between cysteine residues in peptide folding.

By Encyclopeptide Editorial | 1 min read
disulfide cysteine folding modification

Overview

Disulfide bonds form covalent cross-links between cysteine thiol groups, stabilizing protein tertiary and quaternary structure.

Formation

Catalyzed by protein disulfide isomerase (PDI) in the ER. Ero1 provides oxidizing equivalents.

Patterns

  • Intrachain: Stabilize tertiary structure
  • Interchain: Link subunits in quaternary structure
  • Vicinal: Adjacent cysteines in some toxins

Biological Significance

Disulfide bonds are critical for antibody structure, insulin processing, and extracellular protein stability.

References

  • Source: ENCP Peptide Database
  • Category: Peptide Modifications

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