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Peptide-Drug Conjugates advanced

Polatuzumab Vedotin

Anti-CD79b antibody-drug conjugate with MMAE payload for relapsed or refractory diffuse large B-cell lymphoma.

By Encyclopeptide Editorial | 2 min read
ADC antibody-drug-conjugate auristatin DLBCL CD79b

Chemical Identity

PropertyValue
Molecular Weight~150 kDa (ADC)
Peptide PayloadMonomethyl auristatin E (MMAE)
LinkerValine-citrulline (protease-cleavable)
DAR~3.5
TargetCD79b

Structure

Polatuzumab vedotin (Polivy) is a humanized anti-CD79b IgG1 monoclonal antibody conjugated to MMAE via a valine-citrulline cleavable linker. CD79b is a component of the B-cell receptor complex expressed on most B-cell malignancies.

Mechanism of Action

The antibody binds CD79b on B-cell lymphoma cells, inducing receptor-mediated endocytosis. Lysosomal cleavage releases MMAE, which binds tubulin and inhibits microtubule assembly, causing G2/M arrest and apoptosis. The conjugate is combined with bendamustine and rituximab for enhanced efficacy.

Clinical Applications

  • Diffuse large B-cell lymphoma: Relapsed/refractory with bendamustine-rituximab (Polivy)
  • First-line DLBCL: With R-CHP (POLARIX trial)
  • Follicular lymphoma: Under investigation
  • Mantle cell lymphoma: Early clinical data

Pharmacokinetics

  • Half-life: ~12 days
  • Steady state: ~42 days
  • Cmax (MMAE): ~3.5 ng/mL
  • Metabolism: MMAE by CYP3A4
  • Route: IV infusion every 3 weeks (1.8 mg/kg)

Safety and Side Effects

Neutropenia (46%), peripheral neuropathy (40%), fatigue, diarrhea, nausea, thrombocytopenia, anemia, and infections. Tumor lysis syndrome risk with high tumor burden. Requires G-CSF support in most patients.

References

  • Sehn, L.H., et al. (2019). Polatuzumab vedotin with BR for DLBCL. New England Journal of Medicine, 382, 2209-2219.
  • Tilly, H., et al. (2022). POLARIX: polatuzumab vedotin with R-CHP. New England Journal of Medicine, 386, 351-363.

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